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李浩然, 曾议, 朱磊, 等. 光解速率测量技术研究进展[J]. 环境科学与技术, 2024,47(S1):48-58.
李浩然, 曾议, 朱磊, et al. Research Progress of Photolysis Rate Measurement Technology[J]. 2024, 47(S1): 48-58.
李浩然, 曾议, 朱磊, 等. 光解速率测量技术研究进展[J]. 环境科学与技术, 2024,47(S1):48-58. DOI: 10.19672/j.cnki.1003-6504.0696.23.338.
李浩然, 曾议, 朱磊, et al. Research Progress of Photolysis Rate Measurement Technology[J]. 2024, 47(S1): 48-58. DOI: 10.19672/j.cnki.1003-6504.0696.23.338.
光解反应作为大气中链式反应的引发反应,是产生二次污染物的重要原因,光解速率作为描述光解反应强度的关键参数,其数值的准确测量愈加重要。光解速率的测量技术自被研发起不断发展,截至目前常见的测量技术有化学光度计测量技术、滤波辐射计测量技术,以及光谱辐射计测量技术等。其中:化学光度计测量技术是最直接测量光解速率的方法,不过由于其操作流程烦琐、仪器复杂,多用于实验室测量;滤波辐射计测量技术是一种简化的测量技术,具有较宽的光谱覆盖,并且仪器体积小、重量轻,缺点是测量气体种类有限,测量误差较大,多用于机载测量;光谱辐射计测量技术是最通用的测量方法,能够同时测量多种气体的光解速率,并且目前已利用该原理生产出商业化的光解光谱仪,然而光谱辐射计测量技术对光谱仪要求较高,多用于外场实验。除此之外,还可以用经验公式法与脉冲(闪过或激光)光解法来获得特定情况下的光解速率。该文总结了光解速率测量技术在各方面的应用,并对可能的研究重点进行了展望。
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