纸质出版:2024
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王巧敏, 车祥, 陈曦, 等. 化学试剂和助剂制造行业VOCs排放成分谱及影响[J]. 环境科学与技术, 2024,47(S1):111-117.
王巧敏, 车祥, 陈曦, et al. Source Profiles and Impact of VOCs in the Chemical Reagent and Auxiliary Manufacturing Industry[J]. 2024, 47(S1): 111-117.
王巧敏, 车祥, 陈曦, 等. 化学试剂和助剂制造行业VOCs排放成分谱及影响[J]. 环境科学与技术, 2024,47(S1):111-117. DOI: 10.19672/j.cnki.1003-6504.0295.23.338.
王巧敏, 车祥, 陈曦, et al. Source Profiles and Impact of VOCs in the Chemical Reagent and Auxiliary Manufacturing Industry[J]. 2024, 47(S1): 111-117. DOI: 10.19672/j.cnki.1003-6504.0295.23.338.
使用SUMMA罐采集和GC-MS定量分析技术研究了上海市化学试剂和助剂制造行业6家企业有组织废气中的挥发性有机物(VOCs),计算了各企业VOCs排放量和排放系数,并对排放成分谱及臭氧生成潜势(OFP)进行了分析和评价。结果表明,该行业VOCs的基本组分为烷烃、芳香烃、卤代烃和含氧烃(OVOCs),这些组分占总VOCs的99.5%以上;主要特征污染物包括2-甲基戊烷、3-甲基戊烷、正己烷、甲基环戊烷、四氢呋喃、丙酮、乙苯和间/对二甲苯;烷烃、芳香烃和OVOCs是主要的光化学活性组分;四氢呋喃、2-甲基戊烷、3-甲基戊烷、1
2
4-三甲苯、1.2
3-三甲苯等是对OFP贡献较大的因子;源反应性(SR)处于各行业平均水平。研究建议该行业应重点管控C6-C8烷烃、C8-C9芳香烃和OVOCs的排放,并特别关注臭氧生成能力强的VOCs因子,以降低其对环境和人体健康的影响。
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