海底沉积层裂隙中水合物封堵CO<sub>2</sub>效果与失稳条件实验

张菊; 季玉轩; 郭会荣; 李辉; 王哲

doi:10.19509/j.cnki.dzkq.tb20230651

您当前的位置：

首页 >

文章列表页 >

海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验

环境地质与工程 | 更新时间：2026-11-05

- 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验
- 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验
- 地质科技通报 2025年44卷第5期页码：285-292
- 作者机构：
  
  1. 中国地质大学(武汉)环境学院
  2. 中国地质大学(武汉)海洋学院
- 作者简介：
- 基金信息：
  
  国家自然科学基金项目(42177077)
- DOI：10.19509/j.cnki.dzkq.tb20230651
  中图分类号： P736.21;X701
- 网络首发：2025-03-24，
  
  纸质出版：2025-03-24
- 稿件说明：
移动端阅览
张菊, 季玉轩, 郭会荣, 等. 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验[J]. 地质科技通报, 2025,44(5):285-292. DOI: 10.19509/j.cnki.dzkq.tb20230651.

张菊, 季玉轩, 郭会荣, et al. 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验[J]. Bulletin of Geological Science and Technology, 2025, 44(5): 285-292. DOI: 10.19509/j.cnki.dzkq.tb20230651.
张菊, 季玉轩, 郭会荣, 等. 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验[J]. 地质科技通报, 2025,44(5):285-292. DOI: 10.19509/j.cnki.dzkq.tb20230651. DOI：

张菊, 季玉轩, 郭会荣, et al. 海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验[J]. Bulletin of Geological Science and Technology, 2025, 44(5): 285-292. DOI: 10.19509/j.cnki.dzkq.tb20230651. DOI：

摘要

海底二氧化碳（CO

）地质封存技术已成为目前碳封存、碳中和研究的热点，我国南海北部海底沉积层中存在CO

水合物形成的有利空间和温压条件，在裂隙和孔隙中形成CO

水合物，能够阻挡CO

进一步向上运移而产生自封堵能力。然而，目前裂隙中CO

水合物封堵效果与失稳条件仍不明确。采用高压低温水合物生长失稳可视化实验平台，模拟2℃、3～4 MPa的海底沉积盖层条件，观测裂隙中CO

水合物的形成与注水增压失稳过程，利用突破压力、突破压差、持续时间、失稳起始阶段渗透率及封堵率为指标对水合物失稳条件与封堵效果进行了研究。研究结果表明，裂隙中水合物的形成经历成核、扩张、成型与聚集4个阶段；裂隙中形成的水合物能够高效地封堵水和CO

等流体的迁移，但在流体压力逐渐增加达到临界突破压力时开始出现失稳现象，水合物的失稳经历粒度退化与表面摩擦破坏2个阶段，水合物团块内核部先失稳，在水合物表面未破裂前可保持封堵状态；裂隙中水合物失稳的突破压力为6.414～6.966 MPa，突破压差为2.403～3.203 MPa，决定水合物突破压力的关键因素是温度和压力条件，而流速的效应则主要体现在调节水合物进入失稳状态的具体时间；在3～4 MPa的海底沉积盖层条件下，裂隙模型中水合物封堵率为99.0%～99.6%，失稳起始阶段渗透率为0.555×10

-3

～1.260×10

-3

μm

。需要保证封盖CO

水合物层之下压力与海底实际压力之差小于2 MPa，以保持水合物的封堵效果。研究结果为南海类似条件下CO

海底地质封存上覆盖层风险性评价提供参考。

Abstract

ObjectiveSeabed carbon dioxide (CO2) geological sequestration technology has gained popularity in the fields of carbon sequestration and carbon neutralization. In the northern South China Sea

favorable conditions for the formation of CO2 hydrates exist in seabed sediments

where hydrates forming in cracks and pores may block the further upward migration of CO2 and generate self-sealing capacities. However

the effects of CO2 leakage in fractures and the instability of hydrate plugging remain unclear. MethodsA visualization experimental platform for hydrate growth and the instability process under water injection supercharging at high pressure and low temperature was used to observe CO2 hydrate formation. The platform simulated the conditions of seafloor sedimentary cover at 2℃ and 3-4 MPa

and evaluated hydrate instability and plugging effects using parameters of breakthrough pressure

breakthrough pressure difference

duration

permeability coefficient at the initial instability stage

and plugging rate. ResultsThe experimental results show that hydrate formation proceeds through four stages: Nucleation

expansion

formation

and aggregation. Hydrates formed in cracks effectively block the migration of fluids such as water and CO2; however

instability begins when fluid pressure increases and reaches the critical breakthrough pressure. The instability process can be divided into two stages: Particle size degradation and surface friction failure. The hydrate mass core becomes unstable first

while the sealing state persists until the surface of the hydrate fails due to friction. The breakthrough pressure ranges from 6.414 to 6.966 MPa

and the breakthrough pressure difference is between 2.403 and 3.203 MPa. Hydrate instability is primarily influenced by flow rate

with the flow rate affecting the instability rate through interface effects. The breakthrough pressure of hydrates is mainly determined by temperature and pressure

while flow rate influences the exact time when hydrates enter instability. At 3-4 MPa seafloor sedimentary cover

the sealing rate is 99.0%-99.6%

and the permeability coefficient at the initial instability stage ranges from 0.555×10−3 to 1.260×10−3 μm2. ConclusionThe experimental results offer a reference for risk assessments of overlying layers in similar conditions in the South China Sea for CO2 seabed geological sequestration. To maintain the sealing effect of CO2 hydrates

the pressure difference between the capped hydrate layer and the actual seabed pressure should be less than 2 MPa.

关键词

Keywords

references

罗亚南,蒋坤卿,黄思浩,冯波,卜宪标.地热水回灌耦合CO_2地质封存系统安全性分析[J].地质科技通报,2024(03).

祁生文,郑博文,王赞,赵海军,崔振东,黄天明,郭松峰,付雷,董平川.二氧化碳地质利用与封存场址的地质评价[J].中国科学:地球科学,2023(09).

阮博阳,杨盼瑞,郭会荣,王哲.基于PIV技术研究不连通孔隙中残余DNAPL的溶解速率影响因素[J].地质科技通报,2023(04).

郁桂刚,欧文佳,吴翔,宁伏龙,张凌.天然气水合物分解动力学研究进展[J].地质科技通报,2023(03).

雷少飞,孙金声,白英睿,吕开河,张曙沛,许成元,程荣超,刘凡.裂缝封堵层形成机理及堵漏颗粒优选规则[J].石油勘探与开发,2022(03).

张立贺,包瑞新,宋书宇,商丽艳.倾斜管中CO_2水合物生成及堵管实验研究[J].天然气化工—C1化学与化工,2022(01).

周媛,杨盼瑞,郭会荣,原敏,王哲,周萍.注入丁醇调节重非水液相密度的微空隙试验模拟[J].地质科技通报,2022(01).

曹学文,杨凯然,杨健,唐国祥,边江.高压CO_2水合物的生成机理实验和模拟[J].高压物理学报,2021(03).

孙玉景,周立发,李越.CO_2海洋封存的发展现状[J].地质科技情报,2018(04).

李传辉,赵倩,徐红军,冯凯,刘学伟.南海神狐海域地层渗透率与含水合物饱和度关系研究(英文)[J].Applied Geophysics,2014(02).

牛丽伟,卢祥国,熊春明,唐孝芬,吴行才,贾旭,张松.无机凝胶成胶性能及封堵效果实验[J].石油勘探与开发,2013(06).

雷晓,邓建强,张早校.海底沉积物层CO_2封存中水合物研究进展[J].化工进展,2012(06).

李洛丹,刘妮,刘道平.二氧化碳海洋封存的研究进展[J].能源与环境,2008(06).

Zhun Zhang,Zikun Li,Chengfeng Li,Zhuo Zhang,Changling Liu,Wanjun Lu,Fulong Ning.Analysis of permeability anisotropy of marine hydrate-bearing sediments using fractal theory combined with X-CT[J].Ocean Engineering,2024.

Zhou Jilin,Wang Xiujuan,Collett Timothy S.,Li Sanzhong,Kuang Zenggui,Lu Yintao,Deng Wei,Yan Weichao,Qian Jin,Jin Jiapeng.Characterization of a complex sand-rich gas hydrate reservoir system in the Indian marine continental margin with downhole log and seismic data[J].Marine and Petroleum Geology,2023.

Zhao Guojun,Yang Mingjun,Pang Weixin,Gong Guangjun,Zheng Jia-nan,Zhang Peng,Chen Bingbing.Effects of hydrate cap on leakage prevention and capacity improvement of sub-seabed CO2 sequestration[J].Chemical Engineering Journal,2022.

Lim Vincent W.S.,Barwood Mark T.J.,Metaxas Peter J.,Johns Michael L.,Aman Zachary M.,May Eric F..Nucleation rates of carbon dioxide hydrate[J].Chemical Engineering Journal,2022.

Rezaei Amin,Hassanpouryouzband Aliakbar,Molnar Ian,Derikvand Zeinab,Haszeldine R. Stuart,Edlmann Katriona.Relative Permeability of Hydrogen and Aqueous Brines in Sandstones and Carbonates at Reservoir Conditions[J].Geophysical Research Letters,2022(12).

Li Yi,Lv Lei,Ming Liang,Yu Qingchun.Quantitative investigation of phase characteristic effects on CO2 breakthrough pressures in unsaturated Low-Permeability sandstone[J].Journal of Hydrology,2022.

Yujie Bai,Guangsheng Cao,Hongxin An,Haixiang Zhang.Generation laws and distribution characteristics of carbon dioxide hydrate in a reaction kettle[J].Experimental Thermal and Fluid Science,2020.

Michihiro Muraoka,Yoshitaka Yamamoto,Norio Tenma.Simultaneous measurement of water permeability and methane hydrate pore habit using a two-dimensional glass micromodel[J].Journal of Natural Gas Science and Engineering,2020.

Jarand Gauteplass,Stian Almenningen,Geir Ersland,Tanja Barth,Jinhai Yang,Antonin Chapoy.Multiscale investigation of CO 2 hydrate self-sealing potential for carbon geo-sequestration[J].Chemical Engineering Journal,2020.

Xingwei Ren,Zeyu Guo,Fulong Ning,Shuzhi Ma.Permeability of hydrate-bearing sediments[J].Earth-Science Reviews,2020.

Nobuo Maeda.Nucleation curve of carbon dioxide hydrate[J].Energy Procedia,2019.

Stian Almenningen,Jarand Gauteplass,Per Fotland,Gry L. Aastveit,Tanja Barth,Geir Ersland.Visualization of hydrate formation during CO 2 storage in water-saturated sandstone[J].International Journal of Greenhouse Gas Control,2018.

Combustion, Carbon Capture and Storage Centre, Cranfield University, Bedford, Bedfordshire MK43 0AL, UK,Combustion, Carbon Capture and Storage Centre, Cranfield University, Bedford, Bedfordshire MK43 0AL, UK,British Geological Survey, Environmental Science Centre, Nicker Hill, Keyworth, Nottingham NG12 5GG, UK,Combustion, Carbon Capture and Storage Centre, Cranfield University, Bedford, Bedfordshire MK43 0AL, UK.A review of developments in carbon dioxide storage[J].Applied Energy,2017.

Cairong He,Tongke Wang,Zhixue Zhao,Yonghong Hao,Tian-Chyi J. Yeh,Hongbin Zhan.One-dimensional analytical solution for hydraulic head and numerical solution for solute transport through a horizontal fracture for submarine groundwater discharge[J].Journal of Contaminant Hydrology,2017.

Cheng Zhang,Qingchun Yu.The effect of water saturation on methane breakthrough pressure: An experimental study on the Carboniferous shales from the eastern Qaidam Basin, China[J].Journal of Hydrology,2016.

L.P. Hauge,J. Gauteplass,M.D. Høyland,G. Ersland,A. Kovscek,M.A. Fernø.Pore-level hydrate formation mechanisms using realistic rock structures in high-pressure silicon micromodels[J].International Journal of Greenhouse Gas Control,2016.

Mohana L. Delli,Jocelyn L.H. Grozic.Experimental determination of permeability of porous media in the presence of gas hydrates[J].Journal of Petroleum Science and Engineering,2014.

Sheng Dai,Yongkoo Seol.Water permeability in hydrate‐bearing sediments: A pore‐scale study[J].Geophysical Research Letters,2014.

Tohidi Bahman,Yang Jinhai,Salehabadi Manoochehr,Anderson Ross,Chapoy Antonin.CO2 hydrates could provide secondary safety factor in subsurface sequestration of CO2.[J].Environmental science & technology,2010.

Michael, K,Golab, A,Shulakova, V,Ennis-King, J,Allinson, G,Sharma, S,Aiken, T.Geological storage of CO sub(2) in saline aquifers - A review of the experience from existing storage operations[J].International Journal of Greenhouse Gas Control,2010.

S Holloway.Storage capacity and containment issues for carbon dioxide capture and geological storage on the UK continental shelf[J].Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy,2009.

M. Ferdows,M. Ota.Density of CO{sub}2 hydrate by Monte Carlo simulation[J].Proceedings of the Institution of Mechanical Engineers, Part C. Journal of mechanical engineering science,2006.

Ho Teng,Akihiro Yamasaki.PRESSURE-MOLE FRACTION PHASE DIAGRAMS FOR CO 2 -PURE WATER SYSTEM UNDER TEMPERATURES AND PRESSURES CORRESPONDING TO OCEAN WATERS AT DEPTH TO 3000 M[J].Chemical Engineering Communications,2002.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

南海深水超浅层含水合物气层测井识别与饱和度估算方法

掺砂率与干密度对膨润土收缩特性影响

基于文献计量学的地下水年龄研究进展与趋势分析

融合集成机器学习与负样本采样策略的降雨群发滑坡易发性评价

塔里木盆地旗探1井寒武系-震旦系源储系统流体演化与油气成藏机制

海底沉积层裂隙中水合物封堵CO2效果与失稳条件实验

海底沉积层裂隙中水合物封堵CO2效果与失稳条件实验

DOI：10.19509/j.cnki.dzkq.tb20230651

摘要

Abstract

关键词

Keywords

references

海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验

海底沉积层裂隙中水合物封堵CO₂效果与失稳条件实验